Investigating the effect of carbon fabric grammage on the mechanical and erosion properties of CFRP reinforced with ZrB2/SiC ceramic particles at a temperature of 3000°C

Authors

1 department of mechanical engineering, Malek Ashtar university, Tehran, Iran

2 Prof., Mech. Eng., Malek Ashtar University of Technology, Tehran, Iran

3 Assoc. Prof., Mech. Eng Malek Ashtar University of Technology, Tehran, Iran

Abstract

This research investigates the mechanical performance, ablation and oxidation of insulation based on carbon-epoxy Novalac 1179 reinforced with ZrB2/SiC ceramic particles with different grammage of fabric. The purpose of this research is to investigate the effect of carbon fabric grammage on epoxy novalac carbon insulation reinforced with ZrB2/SiC ceramic particles. Three samples including Novalac epoxy resin base with 60% SiC + 40% ZrB2 and 120, 200 and 600 gr/m2 of carbon fabric were made using hot press. The mechanical and thermal properties of insulation samples with different grammage using Oxyacetylene, bending and tensile tests were evaluated. To investigate the surface morphology, X-ray energy distribution elemental analysis (EDS) and SEM scanning electron microscope and X-ray diffraction (XRD) phase analysis have been used to identify the existing phases. The results showed that the mechanical properties and erosion resistance of the composite improved by increasing the grammage of the fabric. The biggest weight reduction and thickness reduction were in the insulation samples with 600 gr/m2 (G3) and 120 gr/m2 fabric(G1), respectively. Also, the G3 sample had the lowest temperature behind the insulation, below 150 degrees Celsius and had the highest mechanical properties, with 486.35 MPa of tensile strength and 677.18 MPa of bending strength. Finally, morphological studies showed that the presence of ZrB2/SiC particles leads to the creation of refractory phases such as ZrO2, SiO2 and ZrSIO4, which increase the resistance to hot erosion of carbon epoxy Novalac composites.

Keywords

Main Subjects


[1]   Patel, R. H. and R. G. Patel, (1993) Carbon fibre reinforced epoxy composites. Polymer international, 30(3): p. 301-303.
[2]   Fiedler, B. , et al. 3825 - Influence of stress state and temperature on the strength of epoxy resins. 2013.
[3]   Liang, S. , et al. (2014) Improving the thermal and mechanical properties of epoxy resins for electronic packaging. in 2014 15th International Conference on Electronic Packaging Technology. IEEE.
[4]   Bakar, M. , et al. , (2009) Mechanical and thermal properties of epoxy resin modified with polyurethane. J. Reinforced Plast. Compo., 28(17): p. 2107-2118.
[5]   Wetzel, B. , F. Haupert, and M. Q. Zhang, (2003) Epoxy nanocomposites with high mechanical and tribological performance. Composites science and technology, 63(14): p. 2055-2067.
[6]   Wu, Y. and Z. Yu, (2015) Thermal conductivity of in situ epoxy composites filled with ZrB2 particles. Composites Science and Technology, 107: p. 61-66.
[7]   Ma, A. -j. , et al. , (2013) Improved thermal conductivity of silicon carbide/carbon fiber/epoxy resin composites. Polymer-Plastics Technology and Engineering, 52(3): p. 295-299.
[8]   Shen, D. , et al. , (2017) Enhanced thermal conductivity of epoxy composites filled with silicon carbide nanowires. Scientific reports, 7(1): p. 2606.
[9]   Feng, T. , et al. , (2013) Oxidation and ablation resistance of ZrB2–SiC–Si/B-modified SiC coating for carbon/carbon composites. Corrosion science, 67: p. 292-297.
[10] Feng, T. , et al. , (2016) Oxidation and ablation resistance of the ZrB2–CrSi2–Si/SiC coating for C/C composites at high temperature. J. Alloys Compounds, 662: p. 302-307.
[11] Zhang, W. -z. , et al. , (2011) Preparation and oxidation property of ZrB2-MoSi2/SiC coating on carbon/carbon composites. Transactions of Nonferrous Metals Society of China, (7):  21p. 1538-1544.
[12] Zou, B. , et al. , (2015) Oxidation protection of carbon/carbon composites with a plasma-sprayed ZrB2–SiC–Si/Yb2SiO5/LaMgAl11O19 coating during thermal cycling. J. Europ. Ceramic Society, 35(7): p. 2017-2025.
[13] Hu, P. , Z. Wang, and X. Sun, (2010) Effect of surface oxidation on thermal shock resistance of ZrB2–SiC–G composite. Int. J. Refractory Metals and Hard Materials, 28(2): p. 280-285.
[14] Yao, X. , et al. , (2014) Oxidation and mechanical properties of SiC/SiC–MoSi2–ZrB2 coating for carbon/carbon composites. J. Mat. Sci. Tech., 30(2): p. 123-127.
[15] Meng, D. , et al. (2016) Tracking and erosion properties evaluation of polymeric insulating materials. in 2016 IEEE International Conference on High Voltage Engineering and Application (ICHVE). IEEE.
[16] El Fgaier, F. , Z. Lafhaj, and C. Chapiseau, (2016) Improvement insulating properties of ceramic materials by incorporating additives. J. Mat. in Civil Eng., 28(8): p. 05016001.
[17] Paiva, J. M. F. , S. Mayer, and M. C. Rezende, (2006) Comparison of tensile strength of different carbon fabric reinforced epoxy composites. Materials Research-ibero-american J. Mat., 9: p. 83-90.
[18] Papargyris, D. A. , et al. , (2008) Comparison of the mechanical and physical properties of a carbon fibre epoxy composite manufactured by resin transfer moulding using conventional and microwave heating. Composites Science and Technology, 68: p. 1854-1861.
[19] Rafique, I. , A. Kausar, and B. Muhammad, (2016) Epoxy Resin Composite Reinforced with Carbon Fiber and Inorganic Filler: Overview on Preparation and Properties. Polymer-Plastics Technology and Engineering, 55: p. 1653 - 1672.
[20] Pervin, F. , et al. , (2005) Testing and evaluation on the thermal and mechanical properties of carbon nano fiber reinforced SC-15 epoxy. Materials Science and Engineering A-structural Materials Properties Microstructure and Processing, 405: p. 246-253.
[21] Choi, S. and J. Kim, (2013) Thermal conductivity of epoxy composites with a binary-particle system of aluminum oxide and aluminum nitride fillers. Composites Part B-engineering, 51: p. 140-147.
[22] Salimi, Kazem, et al. (2023) "Investigation of Adhesion Behavior of Aluminum Laminates/Carbon Fiber/High Silica Fiber by Phenol Resins." Int. J. of Adv. Design & Manufac. Tech., . 16.3: p 55-62.
[23] Rahmani, H. , S. H. M. Najafi, and A. Ashori, (2014) Mechanical performance of epoxy/carbon fiber laminated composites. J. Reinforced Plast. Compo., 33: p. 733-740..
[24] Liu, Y. , et al. , (2016) Erosion resistance of C/C-SiC-ZrB2 composites exposed to oxyacetylene torch. J. The Europ. Ceramic Soc., 36: p. 3815-3821.
[25] Feng, T. , et al. , (2013) Oxidation and ablation resistance of ZrB2–SiC–Si/B-modified SiC coating for carbon/carbon composites. Corrosion Science, 67: p. 292-297.
[26] Ghelich, R. , R. Mehdinavaz Aghdam, and M. R. Jahannama, (2018) Elevated temperature resistance of SiC-carbon/phenolic nanocomposites reinforced with zirconium diboride nanofibers. J. Composite Mater., 52: p. 1239 - 1251.
[27] Chen, Y. , et al. , (2013) Improved ablation resistance of carbon–phenolic composites by introducing zirconium diboride particles. Composites Part B-engineering, 47: p. 100-107.
[28] Shan, X. , et al. , (2017) Preparation and Property Study of Graphene Oxide Reinforced Epoxy Resin Insulation Nanocomposites with High Heat Conductivity. IOP Conference Series: Materials Science and Engineering, 171.
[29] Nassar, A. and E. Nassar. (2013) Study on Mechanical Properties of Epoxy Polymer Reinforced with NanoSiC particles.
[30] Kandola, B. K. , et al. , (2016) Thermal Protection of Carbon Fiber-Reinforced Composites by Ceramic Particles. THE Coatings, 6: p. 22.
[31] Moore, G. R. , D. E. Kline, and P. R. Blankenhorn, (2007) Impregnation of Wood With a High Viscosity Epoxy Resin. Wood and Fiber Science, 15: p. 223-234.
[32]  Bahramian, A. R. , (2012) Ablation Mechanisem of Nanocomposite Heat Shields Based on Thermoset Polymer and Clay. Basparesh, 2(3): p. 4-9.
[33] Kasmaei, MP.J. , Amiri, F. , and Alaei MH. (2024) "Effect of ZrB2 Dominate with SiC Particles on the Ablation and Mechanical Properties of Carbon/Novolac-Epoxy (EPN1179) Composite at 3000 C°." Silicon  1-12.
[34] Hu, P. , W. Guolin, and Z. Wang, (2009) Oxidation mechanism and resistance of ZrB2–SiC composites. Corrosion Science, 51(11): p. 2724-2732.
[35] Yang, X. , et al. , (2013) ZrB2/SiC as a protective coating for C/SiC composites: Effect of high temperature oxidation on mechanical properties and anti-ablation property. Composites Part B: Engineering, 45(1): p. 1391-1396.
[36] Li, H. -j. , et al. , (2013) Effect of heat flux on ablation behaviour and         mechanism of C/C–ZrB2–SiC composite under oxyacetylene torch flame. Corrosion science, 74: p. 265-270.
[37] Mazahery, A. and M. O. Shabani, (2012) Study on microstructure and abrasive wear behavior of sintered Al matrix composites. Ceramics International, 38: p. 4263-4269.
[38] Sharma, S. K. , et al. , (2017) High temperature erosion behavior of spark plasma sintered ZrB2-SiC composites. Ceramics International, 43: p. 8982-8988.
[39] Li, H. , et al. , (2009) Ablation Resistance of Different Coating Structures for C/ZrB2–SiC Composites Under Oxyacetylene Torch Flame. International J. Appl. Ceramic Tech., 6: p. 145-150.
[40] Li, P. , et al. , (2018) Cyclic Ablation Behaviors of ZrB2–SiC Composites Sintered with Nano‐Sized Particles. Advanced Engineering Materials, 20.
[41] Chen, Y. , et al. , (2013) Improved ablation resistance of carbon–phenolic composites by introducing zirconium diboride particles. Composites Part B: Engineering, 47: p. 320-325.
[42] Liu, Y. , et al. , The ablation behavior and mechanical property of C/C-SiC-ZrB2 composites fabricated by reactive melt infiltration. Ceramics International, 2017. 43(8): p. 6138-6, 147-8.
[43] Liu, L. , et al. , (2014) Influence of SiC additive on the ablation behavior of C/C composites modified by ZrB2–ZrC particles under oxyacetylene torch. Ceramics International, 40(1): p. 541-549.
[44] Beaudet, J. , et al. , (2011) Ablation Properties of C Fibers and SiC Fibers Reinforced Glass Ceramic Matrix Composites Upon Oxyacetylene Torch Exposure. Materials Sciences and Applications,02: p. 1399-1406.
[45] Debnath, U. K. , et al. (2017) Study of erosion characterization of carbon fiber reinforced composite material.
[46] Xu, F. L. , et al. , (2020) Ablation Behavior of a Carbon Fabric Reinforced Phenolic Composite Modified by Surface-Decorated ZrB2/SiC. Materials, 13.
[47] Zhang, L. and N. P. Padture, (2017) Inhomogeneous oxidation of ZrB2-SiC ultra-high-temperature ceramic particulate composites and its mitigation. Acta Materialia, 129: p. 138-148.
[48]  Inoue, R. , et al. , (2018) Oxidation of ZrB2 and its composites: a review. J. Mat. Sci., 53: p. 14885-14906.
[49] Yao, X. , et al. , (2012) A SiC–Si–ZrB2 multiphase oxidation protective ceramic coating for SiC-coated carbon/carbon composites. Ceramics International, 38: p. 2095-2100.
[50] Ran, L. , et al. , (2019) Preparation and properties of C/C−ZrB2−SiC composites by high-solid-loading slurry impregnation and polymer infiltration and pyrolysis (PIP). Transactions of Nonferrous Metals Society of China.
[52] Torabi, S. , Z. Valefi, and N. Ehsani, (2021) Evaluation of oxy-acetylene flame angle effect on the erosion resistance of SiC\ZrB2–SiC\ZrB2 multilayer coatings fabricated by the shielding shrouded plasma spray technique. Ceramics International.
[53] Alosime, E. M. , M. S. Alsuhybani, and M. S. Almeataq, The oxidation behavior of ZrB2-SiC ceramic composites fabricated by plasma spray process. Materials, 202. (2):14. 1 p. 392.
[54] Cheng, Y. , et al. , (2022) Long‐term oxidation and ablation behavior of C f /ZrB 2 –SiC composites at 1500, 2000, and 2200°C. Int. J. Appl. Ceramic Tech.
[55] Wei, C. , et al. , (2018) Ablation behavior of laminated Graphite/ZrB2-SiC ceramics in two different directions. Ceramics International, 44(13): p. 15674-15680.
[56] Sun, G. , et al. , (2018) A Multilayer SiC/ZrB2/SiC Ablation Resistance Coating for Carbon/Carbon Composites. Advanced Engineering Materials, 21.
[57] Daniel, A. , et al. , (2019) Effect of zirconium diboride incorporation on thermal stability and ablation characteristics of carbon fiber-reinforced resorcinol–formaldehyde composites. Industrial & Engineering Chemistry Research, 58(40): p. 18623-18634.
[58] Xu, X. Y. , et al. , (2014) Preparation of C@ ZrSiO4 inclusion pigment using compound colorants via non-hydrolytic sol-gel method. Advanced Materials Research, 936: p. 170-175.
[59] Torabi, S. , Z. Valefi, and N. Ehsani, (2021)The effect of the SiC content on the high duration erosion behavior of SiC/ZrB2– SiC/ZrB2 functionally gradient coating produced by shielding shrouded plasma spray method. Ceramics International,.
[60] Gupta, Y. , T. Venkateswaran, and B. V. M. Kumar, (2020) Influence of angle of incidence, temperature and SiC content on erosive wear behavior of ZrB 2 ‐SiC composites. International J. Appl. Ceramic Tech.
[61] Torabi, S. , Z. Valefi, and N. Ehsani, (2020) Ablation behavior of SiC/ZrB2 ultra-high temperature ceramic coatings by solid shielding shrouded plasma spray for high-temperature applications (temperature above 2000° C). Surface and Coatings Technology, 403: p. 126271.
[62]  Wang, S. , H. Huang, and Y. Tian, (2020)Effects of zirconium carbide content on thermal stability and ablation properties of carbon/phenolic composites. Ceramics International, 46(4): p. 4307-4313.
[63] Nguyen, T. P. , et al. , (2020) Electron microscopy investigation of spark plasma sintered ZrO2 added ZrB2–SiC composite. Ceramics International, 2020. 46: p. 19646-19649.
[64] Deng, X. , et al. , (2015) Preparation and characterization of ZrB2–SiC composite powders from zircon via microwave-assisted boro/carbothermal reduction. Ceramics International, 41: p. 14419-14426.
[65] Krishnarao, R. V. , et al. , (2014) Synthesis of ZrB2–SiC composite powder in air furnace. Ceramics International, 2014. 40: p. 15647-15653.
[66]  Ren, X. , et al. , ZrB2–SiC gradient oxidation protective coating for carbon/carbon composites. Ceramics International, 40: p. 7171-7176.
[67] Zhang, D. , et al. , (2019) Oxidation behavior and ablation mechanism of Cf/ZrB2-SiC composite fabricated by vibration-assisted slurry impregnation combined with low-temperature hot pressing. Corrosion Science, 161: p. 108181.
[68]  Xu, F. , et al. , (2020) Ablation behavior and mechanism of TaSi 2-modified carbon fabric-reinforced phenolic composite. J. mate. sci., 55: p. 8553-8563.
[69]  Suresha, B. and M. S. Saini, (2018) Fabrication and mechanical characterisation of carbon fabric reinforced epoxy with alumina and molybdenum disulfide fillers. Int. J. Comput. Aided Eng. Technol. , 10: p. 89-101.
[70] Guo, S. , et al. , Effect of thermal exposure on strength of ZrB2-based composites with nano-sized SiC particles. Composites Science and Technology, 2008. 68: p. 3033-3040.
[71] Wang, L. , et al. , (2017) High‐temperature tensile strength and fracture behavior of ZrB2‐SiC‐graphite composite. Int. J. Appl. Ceramic Tech., 14: p. 31-38.
 
[72] Zou, J. , et al. , (2012) High-temperature bending strength, internal friction and stiffness of ZrB2–20 vol% SiC ceramics. J. The Europ. Ceramic Soc., 32: p. 2519-2527.
[73] Shahabaz, S. , et al. , (2021) Effect of alumina and silicon carbide nanoparticle-infused polymer matrix on mechanical properties of unidirectional carbon fiber-reinforced polymer. J. Compo. Sci., 2022. 6(12): p. 381.
[74] Abdulganiyu, I. , I. Oguocha, and A. Odeshi, (2021) Influence of microfillers addition on the flexural properties of carbon fiber reinforced phenolic composites. J.Compo. Mater., 55: p. 3973 - 3988.