Effect of functionalized Graphene Nanoplates on the Mechanical Properties of Vinil Ester/ Glass Fibers Compositete

Authors

1 Faculty of Materials Science and Engineering, K. N. Toosi University of Technology, Tehran, Iran

2 PhD student, Department of Biomedical Engineering Department, Amirkabir University of Technology, Tehran, Iran.

3 Department of Marine Sciences and Ship Engineering, Amirkabir University of Technology, Tehran, Iran

4 Complex of Material and Manufacturing Technology, Malek Ashtar University, Tehran, Iran

Abstract

In this study, the effect of functionalized graphene nanoplatelets (GNPs) on the mechanical properties of vinyl ester/glass fiber composites was investigated. In order to properly distribute the graphene in the matrix and create a stronger bond between surface modified GNPs, vinyl ester and glass fibers, surface treatment of GNPs was performed using (3-aminopropyl) trimethoxysilane. The nanocomposites with different weight percentages of treated GNPs (0, 0.2, 0.4 and 0.6) were fabricated by hand lay-up method. The nanocomposite with 0.4 wt.% of modified GNPs showed the best mechanical properties. The results of bending test of 0.4 wt.% showed 63 and 28 percent increase in flexural strength and modulus, respetivily compared to composite without GNPs. Also nanocomposite containing 0.4 wt.% surface modified GNPs exhibited 26% and 11% improvement in tensile strength and modulus of elstisty compared to the FMLs containing 0.0 wt.% GNPs, respectively. According to the SEM images, the increase in mechanical properties could be related to the improvement in the adhesion between glass fibers and vinyl ester resin, and also the toughening mechanism of treated GNPs.

Keywords


[1] Abdollahi Azghan M, Asghari F and  Eslami Farsani R (2017) Experimental study of the effect of cryogenic cycling and metal surface treatment on flexural properties of aluminum-epoxy/basalt fibers laminate composite. Iranian Journal of Manufacturing Engineering 4(1): 15-24
[2] Kumar P, Irudhayam J, Naviin D. and Development (2012) a review on importance and recent applications of polymer composites in orthopaedics. International Journal of Engineering Research and Development 5(2): 40-43.
[3] Abadie M, Mekhissi K and Burchill P (2002) Effects of processing conditions on the curing of a vinyl ester resin. Appl Polym 84(6): 1146-1154.
[4] Van Tonder T (2014) Adhesive properties of thermoset fibre metal laminates. Thesis University of Cape Town.
[5] Hosseini Abbandanak SN, Aghamohammadi H, Akbarzadeh E, Shabani N, Eslami-Farsani R, Kangooie M, Siadati MH (2019) Morphological /Saxs/Waxs studies on the electrochemical synthesis of graphene nanoplatelets. Ceramics International 45(16): 20882-20890
[6] Hosseini Abbandanak SH, Abdollahi Azghan M, Eslami-Farsani R (2019) Investigation the interface and charpy impact behavior of fiber metal laminates containing graphene nanoplatelets and glass kevlar hybrid fibers. Iranian Journal of Manufacturing Engineering 6(2):10-19
[7] Huang, X, Qi X, Boey F. and Zhang H (2012) Graphene-based composites. Chemical Society Reviews 41(2): 666-686.
[8] Arkles B (2003) Silane coupling agents: Connecting across boundaries. Morrisville: Gelest: 9-12.
[9] Zahari W, Badri, R, Ardyananta H, Kurniawan D, Nor F (2015) Mechanical properties and water absorption behavior of Polypropylene/Ijuk fiber composite by using silane treatment. Procedia Manuf 2: 573-578.
[10] Rafiee M. A, Rafiee J, Srivastava I, Wang Z, Song H, Yu Z, Koratkar N (2010) Fracture and fatigue in graphene nanocomposites. Small 6(2): 179-183.
[11] Ahmadi-Moghadam B, Sharafimasooleh M and Shadlou S, Taheri F (2015) Effect of functionalization of graphene nanoplatelets on the mechanical response of graphene/epoxy composites. Mater Design 66: 142-149.
[12] Liao W, Tien H, Hsiao S, Li S, Wang Y, Huang Y, Yang S, Ma CM, Wu Y (2013) Effects of multiwalled carbon nanotubes functionalization on the morphology and mechanical and thermal properties of carbon fiber/vinyl ester composites. ACS Appl Mater Interfaces 5(9): 3975-3982.
[13] Pathak A, Borah M, Gupta A, Yokozeki T, Dhakate S (2016) Improved mechanical properties of carbon fiber/graphene oxide-epoxy hybrid composites. Compos Sci Technol 135: 28-38.
[14] حسینی آب‌بندانک س­ن، سیادتی س­م، اسلامی فارسانی ر (1397) اثر اصلاح سطحی گرافن بر رفتار مکانیکی کامپوزیت‌های اپوکسی-الیاف بازالت. مجله علوم و تکنولوژی پلیمر 170-155 :(31)2.
[15] Zaman I, Phan T, Kuan H, Meng Q, La LTB, Luong L, Youssf O, Ma J (2011) Epoxy/Graphene platelets nanocomposites with two levels of interface strength. Polymer 52(7): 1603-1611.
[16] https://www.us-nano.com/inc/sdetail/3767
[17] ASTM D 790 (2000) Standard test methods for flexural properties of un-reinforced and reinforced plastics and electrical insulating materials. Annual Book of ASTM Standard.
[18] ASTM D3039 (2008) standard test method for tensile properties of polymer matrix composite materials. Annual Book of ASTM International.
[19] Coates J (2006) Interpretation of infrared      spectra a practical approach. encyclopedia of analytical chemistry: Applications, theory and instrumentation.
 [20] Hosseini Abbandanak SN, Abdollahi Azghan M, Zamani A, Fallahnejad M, Eslami-Farsani R, Siadati SM (2020) Effect of graphene on the interfacial and mechanical properties of hybrid glass/kevlar fiber metal laminates. J Ind Text.
[21] Davim JP, Reis P (2003) Study of delamination in drilling carbon fiber reinforced plastics (CFRPs) using design experiments. Compos Struct 59(4): 481-487.
[22] Choi N, Kinloch A, Williams J (1999) Delamination fracture of multidirectional carbon-fiber/epoxy composites under Mode I, Mode Ii and Mixed-Mode I/Ii Loading. J Compos Mater 33(1): 73-100.
[23] Quaresimin M, Schulte K, Zappalorto M, Chandrasekaran S (2016) Toughening mechanisms in polymer nanocomposites: From experiments to modeling. Compos Sci Tech 123:187-204.
[24] Shen M, Kuan C, Kuan H, Chen C, Wang J, Yip M, Chiang C (2013) Preparation, characterization, thermal, and flame-retardant properties of green silicon-containing epoxy/functionalized graphene nanosheets composites. J Nanomater 2013: 1-10
 [25] Ammar A, Al Enizi A, Al Maadeed M, Karim A (2016) Influence of graphene oxide on mechanical, morphological, barrier, and electrical properties of polymer membranes. Arab J Chem 9(2): 274-286.
[26] Bulut E (2017) Mechanical characterization of basalt/epoxy composite laminates containing graphene nanopellets. Compos Part B-Eng (122): 71-78.
[27] Siddiqui A, Sham M, Tang B, Munir A, Kim J (2009) Tensile strength of glass fibres with carbon nanotube–epoxy nanocomposite coating. Compos Part A-Appl S 40(10): 1606-1614.